Mr. Guch's Great
Big Vocabulary List
-
absolute temperature:
This is a temperature reading made relative to absolute zero. We
use the unit of Kelvins for these readings.
-
absolute zero: This is
the lowest temperature possible. If you remember that temperature
is a measurement of how much atoms move around in a solid, you can guess
that they stop moving entirely at absolute zero. In reality, bonds
still vibrate a little bit, but for the most part you don't see much happening.
-
accuracy: When you measure
something, the accuracy is how close your measured value is to the real
value. For example, if you're actually six feet tall and your brother
measures your height as six feet, one inch, he's pretty accurate.
However, if your cousin measures your height as twelve feet, 13 inches,
he's not accurate at all.
-
acid: This is anything
that gives off H+ ions in water. Acids have a pH less than 7 and
are good at dissolving metals. They turn litmus paper red and phenolphthalein
colorless.
-
acid anhydride: This is
an oxide that forms an acid when you stick it in water. An example
is SO3 - when you add water it turns into sulfuric acid, H2SO4.
-
acid dissociation constant (Ka):
This is equal to the ratio of the concentrations of an acid's conjugate
base and the acid present when a weak acid dissociates in water.
That is, if you have a solution of Acid X where the concentration of the
conjugate base is 0.5 M and the concentration of the acid is 10 M, the
acid dissociation constant is 0.5/10 = 0.05.
-
activated complex: In
a chemical reaction, the reagents have to join together into a great big
blob before they can fall back apart into the products. This great
big blob is called the activated complex (a.k.a. transition state)
-
activation energy: The
minimum amount of energy needed for a chemical reaction to take place.
For some reactions this is very small (it only takes a spark to make gasoline
burn). For others, it's very high (when you burn magnesium, you need
to hold it over a Bunsen burner for a minute or so).
-
activity series: This
is when you arrange elements in the order of how much they tend to react
with water and acids.
-
actual yield: When you
do a chemical reaction, this is the amount of chemical that you actually
make (i.e. The amount of stuff you can weigh).
-
addition reaction: A reaction
where atoms add to a carbon-carbon multiple bond.
-
adsorption: When one substance
collects of the surface of another one.
-
alcohol: An organic molecule
containing an -OH group
-
aldehyde: An organic molecule
containing a -COH group
-
alkali metals: Group I
in the periodic table.
-
alkaline earth metals:
Group II in the periodic table.
-
alkane: An organic molecule
which contains only single carbon-carbon bonds.
-
alkene: An organic molecule
containing at least one C=C bond
-
alkyne: An organic molecule
containing at least one C-C triple bond.
-
allotropes: When you have
different forms of an element in the same state. The relationship
that white phosphorus and red phosphorus have to each other is that they're
allotropes.
-
alloy: A mixture of two
metals. Usually, you add very small amounts of a different element
to make the metal stronger and harder.
-
alpha particle: A radioactive
particle equivalent to a helium nucleus (2 protons, 2 neutrons)
-
amine: An organic molecule
which consists of an ammonia molecule where one or more of the hydrogen
atoms has been replaced by organic groups.
-
amino acid: The basic
building blocks of proteins. They're called "amino acids" because
they're both amines (they contain nitrogen) and acids (carboxylic acids,
to be precise)
-
amphiprotic: When something
is both an acid and a base. Like amino acids, for example.
-
amphoteric: When something
is both an acid and a base. Sounds familiar, huh?
-
anode: The electrode where
oxidation occurs. In other words, this is where electrons are lost
by a substance.
-
aqueous: dissolved in
water
-
atomic mass unit (a.m.u.):
This is the smallest unit of mass we use in chemistry, and is equivalent
to 1/12 the mass of carbon-12. To all intents and purposes, protons
and neutrons weigh 1 a.m.u.
-
atomic radius: This is
one half the distance between two bonded nuclei. Why don't we just
measure the distance from the nucleus to the outside of the atom - after
all, isn't that the same thing as a radius? It is, but atoms are
also (theoretically) infinitely large (due to quantum mechanics), making
this impossible to measure.
-
atomic solid: A solid
where there's a bunch of atoms in the lattice. This is different
from an ionic solid, where ions are the things that are sticking together.
-
Aufbau principle: When
you add protons to the nucleus to build up the elements, electrons are
added into orbitals.
-
Avogadro's Law: If you've
got two gases under the same conditions of temperature, pressure, and volume,
they've got the same number of particles (atoms or molecules). This
law only works for ideal gases, none of which actually exist.
-
base anhydride: An oxide
that forms a base when water is added. CaO is an example, turning
into calcium hydroxide in water.
-
base: A compound that
gives off OH- ions in water. They are slippery and bitter and have
a pH greater than 7.
-
battery: This is when
a bunch of voltaic cells are stuck together.
-
beta particle: A radioactive
particle equivalent to an electron.
-
bidentate ligand: A ligand
that can attach twice to a metal ion.
-
binary compound: A compound
only having two elements
-
binding energy: The amount
of energy that holds the neutrons and protons together in the nucleus of
an atom. It's a lot of energy, which is why you don't see nuclei
falling apart all over the place.
-
bond energy: The amount
of energy it takes to break one mole of bonds.
-
bond length: The average
distance between the nuclei of two bonded atoms.
-
Boyle's Law: The volume
of a gas at constant temperature varies inversely with pressure.
In other words, if you put big pressure on something, it gets small.
-
Bronsted-Lowry acid: Acids
donate protons [H+ ions] and bases grab them
-
buffer: A liquid that
resists change in pH by the addition of acid or base. It consists
of a weak acid and it's conjugate base (acetic acid and sodium acetate,
for example).
-
calorimetry: The study
of heat flow. Usually you'd do calorimetry to find the heat of combustion
of a compound or the heat of reaction of two compounds.
-
carboxylic acid: An organic
molecule with a -COOH group on it. Acetic acid is the most famous
one.
-
catalyst: A substance
that speeds up a chemical reaction without being used up by the reaction.
Enzymes are catalysts because they allow the reactions that take place
in the body to occur fast enough that we can live.
-
cathode: The electrode
in which reduction occurs. Reduction is when a compound gains electrons.
-
chain reaction: A reaction
in which the products from one step provide the reagents for the next one.
This is frequently referred to in nuclear fission (when large nuclei break
apart to form smaller ones) and in free-radical reactions.
-
Charles's Law: The volume
of a gas at constant pressure is directly proportional to the temperature.
In other words, if you heat something up, it gets big.
-
chemical equation: The
recipe that describes what you need to do to make a reaction take place.
-
chemical properties: Properties
that can only be described by making a chemical change (by making or breaking
bonds). For example, color isn't a chemical property because you
don't need to change something chemically to see what color it is.
Flammability, on the other hand, is a chemical property, because you can't
tell if something burns unless you actually try to burn it.
-
chirality: When a molecule
has a nonsuperimposable mirror image. To imagine this, put your hands
together. Although they are mirror images, you can't put them right
on top of each other so they are interchangable. Well, normal people
can't, anyway.
-
chromatography: This is
when you use a system containing a mobile phase (usually a liquid in general
chemistry classes) and a stationary phase (something dissolved in the liquid)
to separate different compounds. This is usually done by exploiting
the differing polarities of solutes, though you can do it a whole slew
o' ways.
-
circuit: The closed path
in a circuit through which electrons flow.
-
coagulation: When you
destroy a colloid by letting the particles settle out.
-
colligative property:
Any property of a solution that changes when the concentration changes.
Examples are color, flavor, boiling point, melting point, and osmotic pressure.
-
colloid: It's a suspension.
-
combustion: When a compound
combines with oxygen gas to form water, heat, and carbon dioxide
-
common ion effect: When
the equilibrium position of a process is altered by adding another compound
containing one of the same ions that's in the equilibrium.
-
complex ion: An ion in
which a central atom (usually a transition metal) is surrounded by a bunch
of molecules like water or ammonia (called "ligands")
-
concentration: A measurement
of the amount of stuff (solute) dissolved in a liquid (solvent).
The most common concentration unit is molarity (M), which is equal to the
number of moles of solute divided by the number of liters of solution.
-
condensation: When a vapor
reforms a liquid. This is what happens on your bathroom mirror when
you take a shower.
-
conductance: A measurement
of how well electricity can flow through an object.
-
conjugate acid: The compound
formed when a base gains a proton (hydrogen atom).
-
conjugate base: The compound
formed when an acid loses a proton (hydrogen atom).
-
continuous spectrum: A
spectrum that gives off all the colors of light, like a rainbow.
This is caused by blackbody emission.
-
covalent bond: A chemical
bond formed when two atoms share two electrons.
-
critical mass: The minimum
amount of radioactive material needed to undergo a nuclear chain reaction.
-
critical point: The end
point of the liquid-vapor line in a phase diagram. Past the critical
point, you get something called a "supercritical liquid", which has weird
properties.
-
crystal lattice: see "lattice"
-
crystal: A large chunk
of an ionic solid.
-
Dalton's law of partial pressures:
The total pressure in a mixture of gases is equal to the sums of the partial
pressures of all the gases put together.
-
decomposition: When a
big molecule falls apart to make two or more little ones.
-
degenerate: Things (usually
orbitals) are said to be degenerate if they have the same energy.
This term is used a whole lot in quantum mechanics. Also when dealing
with kids who steal cars.
-
delocalization: This is
when electrons can move around all over a molecule. This happens
when you have double bonds on adjacent atoms in a molecule (conjugated
hydrocarbon)
-
denature: When the 3-D
structure of a protein breaks down due to heat (or pH, etc), it's said
to be denatured. This means that it unravels because the intermolecular
forces between atoms in the chain aren't strong enough to hold it together
anymore.
-
diffusion: When particles
move from areas of high concentration to areas of low concentration.
For example, if you open a bottle of ammonia on one end of the room, the
concentration of ammonia molecules in the air is very high on that side
of the room. As a result, they tend to migrate across the room, which
explains why you can smell it after a little while. Be careful not
to mix this up with effusion (see definition)
-
dilution: When you add
solvent to a solution to make it less concentrated.
-
dipole moment: When a
molecule has some charge separation (usually because the molecule is polar),
it's said to have a dipole moment.
-
dipole-dipole force: When
the positive end of a polar molecule becomes attracted to the negative
end of another polar molecule.
-
dissociation: When water
dissolves a compound.
-
distillation: This is
when
you separate a mixture of liquids by heating it up. The one with
the lowest boiling point evaporates first, followed by the one with the
next lowest boiling point, etc.
-
double-displacement reaction (a.k.a.
double replacement reaction): When the cations of two ionic
compounds switch places.
-
effusion: When a gas moves
through an opening into a chamber that contains no pressure. Effusion
is much faster than diffusion because there are no other gas molecules
to get in the way.
-
electrolysis: When electricity
is used to break apart a chemical compound.
-
electrolyte: An ionic
compound that dissolves in water to conduct electricity. Strong electrolytes
break apart completely in water; weak electrolytes only fall apart
a little bit.
(Actually, this isn't entirely
true, as Raji Heyovska informs me. Apparently strong electrolytes
also dissociate partially in water, though much more so than weak ones.
For more info, check out his paper at http://www.jh-inst.cas.cz/~rheyrovs.
However, it is also true that the usual definition of a strong electrolyte
is one that dissociates completely in water, which is why I include that
definition above.)
-
electron affinity: The
energy change that accompanies the addition of an electron to an atom in
the gas phase.
-
electronegativity: A measurement
of how much an atom tends to steal electrons from atoms that it's bonded
to. Elements at the top right of the periodic table (excluding the
noble gases) are very electronegative while atoms in the bottom left are
not very electronegative (a.k.a. "electropositive")
-
electropositive: When
something is not at all electronegative. In fact, it tends to lose
electrons rather than to gain them. Elements that are electropositive
are generally to the left and bottom of the periodic table.
-
empirical formula: A reduced
molecular formula. If you have a molecular formula and you can reduce
all of the subscripts by some constant number, the result is the empirical
formula.
-
emulsion: When very small
drops of a liquid are suspended in another. An example of an emulsion
is salad dressing after you've shaken it up.
-
enantiomers: molecules
that are nonsuperimposable mirror images of each other.
-
endothermic: When a process
absorbs energy (gets cold).
-
endpoint: The point where
you actually stop a titration, usually because an indicator has changed
color. This is different than the "equivalence point" because the
indicator might not change colors at the exact instant that the solution
is neutral.
-
energy level: A possible
level of energy that an electron can have in an atom.
-
enthalpy: A measurement
of the energy content of a system.
-
entropy: A measurement
of the randomness in a system.
-
enzyme: A biological molecule
that catalyzes reactions in living creatures.
-
equilibrium: When the
forward rate of a chemical reaction is the same as the reverse rate.
This only takes place in reversible reactions because these are the only
type of reaction in which the forward and backward reactions can both take
place.
-
equivalence point: The
point in a titration at which the solution is completely neutral.
This is different than the "endpoint" (see above).
-
ester: An organic molecule
with R-CO-OR' functionality.
-
excess reagent: Sometimes
when you do a chemical reaction, there's some of one reagent left over.
That's called the excess reagent.
-
excited state: A higher
energy level that electrons can jump to when energy is added.
-
exothermic: When a process
gives off energy (gets hot).
-
family: The same thing
as a "group" (see above)
-
first law of thermodynamics:
The energy of the universe is constant. It's the same thing as the
Law of conservation of energy.
-
fission: A nuclear reaction
where a big atom breaks up into little ones. This is what happens
in nuclear power plants.
-
free energy: also called
"Gibbs free energy", it's the capacity of a system to do work.
-
free radical: An atom
or molecule with an unpaired electron. They're way reactive.
-
functional group: A generic
term for a group of atoms that cause a molecule to react in a specific
way. It's really common to talk about this in organic chemistry,
where you have "aldehydes, carboxylic acids, amines" and so on.
-
gamma ray: High energy
light given off during a nuclear process. When a nucleus gives off
this light, it goes to a lower energy state, making it more stable.
-
geometrical isomer: isomerism
where atoms or groups of atoms can take up different positions around a
double bond or a ring. This is also called cis- trans- isomerism.
-
ground state: The lowest
energy state possible for an electron.
-
group: A column (the things
up and down) in the periodic table. Elements in the same group tend
to have the same properties. These are also called "families".
-
half-life: The time required
for half of the radioactive atoms in a sample to decay. When talking
about chemical reactions, it's the amount of time required to make half
the reagent react.
-
half-reaction: The oxidation
or reduction part of a redox reaction.
-
halogen: The elements
in group 17. They're really reactive.
-
heat of reaction: The
amount of heat absorbed or released in a reaction. Also called the
"enthalpy of reaction"
-
heat: The kinetic energy
of the particles in a system. The faster the particles move, the
higher the heat.
-
Hess's Law: The enthalpy
change for a change is the same whether it takes place in one big step
or in many small ones.
-
heterogeneous mixture:
A mixture where the substances aren't equally distributed.
-
homogeneous mixture: A
mixture that looks really "smooth" because everything is mixed up really
well.
-
Hund's rule: The most
stable arrangement of electrons occurs when they're all unpaired.
-
hybrid orbital: An orbital
caused by the mixing of s, p, d, and f-orbitals.
-
hydration: When a molecule
has water molecules attached to it.
-
hydrocarbon: A molecule
containing carbon and hydrogen.
-
hydrogen bond: The tendency
of the hydrogen atom stuck to an electronegative atom to become attracted
to the lone pair electrons on another electronegative atom. It's
a pretty strong intermolecular force, which explains why water has such
a high melting and boiling point.
-
hydrogenation: When hydrogen
is added to a carbon-carbon multiple bond.
-
hydronium ion: The H+
ion, made famous by acids.
-
hydroxide ion: The OH-
ion, made famous by bases.
-
ideal gas law: PV=nRT
-
ideal gas: A gas in which
the particles are infinitely small, have a kinetic energy directly proportional
to the temperature, travel in random straight lines, and don't attract
or repel each other. Needless to say, there's no such thing as an
ideal gas in the real world. However, we use ideal gases anyway because
they make the math work out well for equations that describe how gases
behave.
-
ideal solution: A solution
in which the vapor pressure is directly proportional to the mole fraction
of solvent present
-
immiscible: When two substances
don't dissolve in each other. Think of oil and water. They're
immiscible. Organic compounds and water are frequently immiscible.
-
indicator: A compound
that turns different colors at different pH values. We generally
like to have the color change at a pH of around seven because that's where
the equivalence point of a titration is.
-
inhibitor: A substance
that slows down a chemical reaction.
-
inorganic compound: Any
compound that doesn't contain carbon (except for carbon dioxide, carbon
monoxide, and carbonates).
-
insoluble: When something
doesn't dissolve.
-
intermediate: A molecule
which exists for a short time in a chemical reaction before turning into
the product.
-
intermolecular force:
A force that exists between two different molecules. Examples are
hydrogen bonding (which is strong), dipole-dipole forces (which are kind
of weak), and London dispersion forces (a.k.a. Van der Waal forces), which
are very weak.
-
ionic bond: A bond formed
when charge particles stick together.
-
ionization energy: The
amount of energy required to pull an electron off of a gaseous atom.
-
irreversible reaction:
A chemical reaction in which the reagents make products but the products
can't reform reagents. Most chemical reactions in basic chemistry
classes are thought of as being irreversible.
-
isotonic solutions: Solutions
containing the same osmotic pressure.
-
isotope: When an element
has more than one possibility for the number of neutrons, these are called
isotopes. All known elements posess isotopes. For the record,
the word "isotope" doesn't imply that something is radioactive. TV
told you that, and TV is stupid.
-
Kelvin:
A unit used to measure temperature. One Kelvin is equal in size to
one degree Celsius. To convert between degrees Celsius and Kelvins,
simply add 273.15 to the temperature in degrees Celsius to get Kelvins.
-
ketone: A molecule containing
a R-CO-R' functional group. Acetone (dimethyl ketone) is a common
one.
-
kinetic energy: The energy
due to the movement of an object. The more something moves, the more
kinetic energy it has.
-
Lanthanide contraction:
The tendency of the lanthanides to get small when you go from left to right
in the periodic table.
-
lattice energy: The energy
released when one mole of a crystal is formed from gaseous ions.
-
lattice: The three-dimensional
arrangement of atoms or ions in a crystal.
-
law of conservation of energy:
The amount of energy in the universe never changes, ever. It just
changes form.
-
law of conservation of mass:
The amount of stuff after a chemical reaction takes place is the same as
the amount of stuff you started with.
-
Le Chatlier's Principle:
When you disturb an equilibrium (by adding more chemical, by heating it
up, etc.), it will eventually go back into equilibrium under a different
set of conditions.
-
Lewis acid: An electron-pair
acceptor (carbonyl groups are really good ones)
-
Lewis base: An electron-pair
donor. Things with lone pairs like water and ammonia are really good
ones.
-
Lewis structure: A structural
formula that shows all of the atoms and valence electrons in a molecule.
-
ligand: A molecule or
ion that sticks to the central atom in a complex. Common examples
are ammonia, carbon monoxide, or water.
-
limiting reagent: If you
do a chemical reaction and one of the chemicals gets used up before the
other one, the one that got used up is called the "limiting reagent" because
it limited the amount of product that could be formed. The other
one is called the excess reagent.
-
line spectrum: A spectrum
showing only certain wavelengths.
-
London dispersion force:
The forces between nonpolar atoms or molecules which is caused by momentary
induced dipoles. It's real weak.
-
lone pair: two electrons
that aren't involved in chemical bonding. Also frequently referred
to as an "unshared pair".
-
main-block elements: Groups
1,2, and 13-18 in the periodic table. They're called main block elements
because the outermost electron is in the s- or p- orbitals. What
that has to do with the term "main block" is unclear to me, but hey, that's
life.
-
mass defect: The difference
between the mass of an atom and the sum of the masses of its individual
components. Atoms usually weigh a little less than if you added up
the weights of all the particles. This is because that extra mass
was converted into the energy which holds the atom together (see "binding
energy")
-
mass: The amount of matter
in an object. The more mass, the more stuff is present.
-
mechanism: A step-by-step
sequence that shows how the products of a reaction are made from the reagents.
Mechanisms are very frequently shown during organic chemistry.
-
molality: The number of
moles of solute per kilogram of solvent in a solution. This is a
unit of concentration that's not anywhere near as handy or common as molarity.
-
molar mass: The mass of
one mole of particles.
-
molar volume: The volume
of one mole of a substance at STP. If you believe that everything
is an ideal gas, this is always 22.4 liters. Unfortunately, there's
no such thing as an ideal gas.
-
molarity: A unit of concentration
equal to moles of solute divided by liters of solution.
-
mole fraction: The number
of moles of stuff in a mixture that are due to one of the compouds.
-
mole ratio: The ratio
of moles of what you've been given in a reaction to what you want to find.
Handy in stoichiometry.
-
mole: 6.02 x 1023
things.
-
molecular compound: A
compound held together by covalent bonds.
-
molecular formula: A formula
that shows the correct quantity of all of the atoms in a molecule.
-
monatomic ion: An ion
that has only one atom, like the chloride ion.
-
neutralization reaction:
The reaction of an acid with a base to form water and a salt.
-
node: A location in an
orbital where there's no probability of finding an electron.
-
nonpolar covalent bond:
A covalent bond where the electrons are shared equally between the two
atoms.
-
normal boiling point:
The boiling point of a substance at 1.00 atm.
-
normal melting point:
The melting point of a substance at 1.00 atm.
-
normality: The number
of equivalents of a substance dissolved in a liter of solution.
-
nuclar fusion: When many
small atoms combine to form a large one. This occurs during a thermonuclear
reaction.
-
nuclear fission: This
is when the nucleus of an atom breaks into many parts.
-
nuclear reaction:
Any reaction that involves a change in the nucleus of an atom. Nuclear
reactions take loads of energy, which is why you don't see them much around
the lab.
-
nucleon: A particle (such
as proton or neutron) that's in the nucleus of an atom.
-
octet rule: All atoms
want to be like the nearest noble gas. (Well, they all want to have
the same number of valence electrons, anyway). To do this, they either
gain or lose electrons (to form ionic compounds) or share electrons (to
form covalent compounds).
-
optical isomerism: Isomerism
in which the isomers cause plane polarized light to rotate in different
directions.
-
orbital: This is where
the electrons in an atom live.
-
organic compound: A compound
that contains carbon (except carbon dioxide, carbon monoxide, and carbonates)
-
osmosis: The flow of a
pure liquid into an area of high concentration through a semi-permeable
membrane.
-
oxidation number: The
apparent charge on an atom.
-
oxidation: When a substance
loses electrons.
-
partial pressure: The
pressure of one gas in a mixture. For example, if you had a 50:50
mix of helium and hydrogen gases and the total pressure was 2 atm, the
partial pressure of hydrogen would be 1 atm.
-
Pauli exclusion principle:
No two electrons in an atom can have the same quantum numbers.
-
percent yield: The actual
yield divided by the theoretical yield, times 100.
-
period: A row (left to
right) in the periodic table.
-
periodic law: The properties
of elements change with increasing atomic number in a periodic way.
That's why you can stick the elements into a big chart and have the elements
line up in nice families.
-
pH: -log[H+]
-
phase diagram: A chart
which shows how the phase depends on various conditions of temperature
and pressure.
-
phase: The state of a
compound (solid, liquid, or gas)
-
physical property: A property
which can be determined without changing something chemically. If
that doesn't make sense, see the definition of "chemical change".
-
pi-bond: A double bond.
-
polar covalent bond: A
covalent bond where one atom tries to grab the electrons from the other
one. This occurs because the electronegativities of the two atoms
aren't the same.
-
polyatomic: contains more
than one atom.
-
polymer: A molecule containing
many repeating units. Plastics are polymers and are formed by free
radical chain reactions.
-
polyprotic acid: An acid
that can give up more than one hydronium ion. Examples are sulfuric
acid and phosphoric acid.
-
potential energy: The
energy something has because of where it is. Things that are way
up high have more potential energy than things that are way down low because
they have farther to fall.
-
precision: A measurement
of how repeatable a measurement is. The more significant figures,
the more precise the measurement.
-
pressure: Force/area
-
product: The thing you
make in a chemical reaction.
-
quantum theory: The branch
of physical chemistry that describes how energy can only exist at certain
levels and makes generalizations about how atoms behave from this assumption.
-
radioactive: When a substance
has an unstable nucleus that can fall apart, it's referred to as radioactive.
-
Raoult's Law: The vapor
pressure of a solution is directly proportional to the mole fraction of
the solvent.
-
rate determining step:
The slowest step in a chemical reaction.
-
rate law: A mathematical
expression for the speed of a reaction as a function of concentration.
A hint: It's usually true that things go faster if you have more
stuff in the first place.
-
redox reaction: A reaction
that has both an oxidation and reduction.
-
resonance structure: When
more than one valid Lewis structure can be drawn for a molecule, these
structures are said to be resonance structures. Resonance structures
arise from the fact that the electrons are delocalized.
-
reversible reaction: A
reaction in which the products can make reagents, as well as the reagents
making products.
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root mean square velocity (RMS velocity):
The square root of the average of the squares of the individual velocities
of the gas particles in a mixture. To put it in a way that a normal
human can understand, it's the average of how fast the particles in a gas
are going (assuming you ignore the direction they're traveling in).
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salt: An ionic compound.
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saturated: When the maximum
amount of solute is dissolved in a liquid
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Second law of thermodynamics:
Whenever you do something, the universe gets more random.
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semiconductor: A substance
that conducts electricity poorly at room temperature, but has increasing
conductivity at higher temperatures. Metalloids are usually good
semiconductors.
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shielding effect: The
outer electrons aren't pulled very tightly by the nucleus because the inner
electrons repel them. This repulsion is called the shielding effect,
and can be used to explain lots of neat-o stuff.
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sigma bond: A real fancy
way of saying "single bond"
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significant figure: The
number of digits in a number that tell you useful information. For
example, when you weigh yourself on a bathroom scale, it says something
like 150 pounds rather than 150.32843737 pounds. Why? Because
the thing can only weigh accurately to the nearest pound. Any other
digits that are on this number don't mean anything, because they're probably
wrong anyway.
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single-displacement reaction (a.k.a.
single replacement reaction): When one unbonded element replaces
an element in a chemical compound. These are frequently redox reactions.
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solubility: A measurement
of how much of a solute can dissolve in a liquid.
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solubility product constant:
Abbreviated Ksp, this value indicates the degree to which a
compound dissociates in water. The higher the solubility product
constant, the more soluble the compound.
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solute: The solid that
gets dissolved in a solution.
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solvent: The liquid that
dissolves the solid in a solution.
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specific heat capacity:
The amount of heat required to increase the temperature of one gram of
a substance by one degree.
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spectator ions: The ions
in a reaction that don't react.
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spontaneous change: A
change that occurs by itself. All exothermic reactions are spontaneous.
However, this doesn't mean that all exothermic reactions are fast.
The combustion of gasoline is spontaneous, but not very fast unless you
add a little energy.
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standard temperature and pressure:
One atmosphere and 273 K.
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steric hindrance: This
is the idea that the functional groups on big molecules get in the way
of a chemical reaction, making it go slower. Imagine a fat guy trying
to get into a Honda Prelude - that's steric hindrance.
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stoichiometry: The art
of figuring how much stuff you'll make in a chemical reaction from the
amount of each reagent you start with.
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STP: See standard temperature
and pressure.
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strong acid: An acid that
fully dissociates in water
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strong nuclear force:
The force that holds the nucleus together. As the name suggests,
this force is strong.
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structural formula: See
Lewis structure.
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sublimation: When a solid
can change directly into a gas. Dry ice does this.
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supercooling: When you
cool something below its normal freezing point
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supersaturated: When more
solute is dissolved in a liquid than is theoretically possible. This
doesn't happen much, as you might imagine.
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surface tension: A measurement
of how much the molecules on a liquid tend to like to stick to each other.
If something has a high surface tension, it likes to bead up.
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suspension: A mixture
that looks homogeneous when you stir it, but where the solids settle out
when you stop. Mud is a very short-lived suspension, while peanut
butter is a very long-lived suspension.
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synthesis: When you make
a big molecule from two or more smaller ones.
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system: Everything you're
talking about at the moment.
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temperature: A measurement
of the average kinetic energy of the particles in a system.
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theoretical yield: The
amount of product which should be made in a chemical reaction if everything
goes perfectly.
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thermodynamics: The study
of energy
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Third law o' thermodynamics:
The randomness of a system at 0 K is zero.
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titration: When the concentration
of an acid or base is determined by neutralizing it.
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transition state: See
"activated complex"
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triple point: The temperature
and pressure at which all three states of a substance can exist in equilibrium.
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unit cell: The simplest
part of a crystal that can be repeated over and over to make the whole
thing.
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unsaturated: When you
haven't yet dissolved all of the solute that's possible to dissolve in
a liquid.
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unshared electron pair:
two electrons that aren't involved in chemical bonding. Also frequently
referred to as a "lone pair".
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valence electron: The
outermost electrons in an atom.
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vapor pressure: The pressure
of a substance that's present above it's liquid. For example, you
can tell that ammonia has a high vapor pressure because the smell of it
is very strong above liquid ammonia.
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vaporization: When you
boil a liquid.
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volatile: A substance
with a high vapor pressure.
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VSEPR: A theory for predicting
molecular shapes that assumes that electrons like to be as far from each
other as possible.
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